What is the correct systematic name for Hg(H2PO4)2?

If you get 2x di in succession in a systematic name, this sounds a bit strange. For example, Hg(H2PO4)2 would then be named mercury diphosphate. Suppose you are not allowed to use the stock notation, is this name correct? Another example is Pb(Cr2O7)2.

Asker: Hilde, 42 years old

Answer

Hi Hilde,

Complex substituents use the prefixes “bis”, “tris”, “tetrakis”. The mercury compound is therefore called mercury bis(dihydrogen phosphate) and the lead compound lead bis(dichromate). The substituent that comes after bis etc. is placed in parentheses.

Of course, the Stock notation is simpler in most cases.

What is the correct systematic name for Hg(H2PO4)2?

Answered by

Dr. Etienne Jooken

Chemistry

Catholic University of Leuven
Old Market 13 3000 Leuven
https://www.kuleuven.be/

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