Why does diamond disintegrate when heated to carbon atoms instead of melting first?

Why don’t the atoms go to the liquid phase?

Asker: Laurens, 16 years old

Answer

Hi Lauren,

Diamond is actually one of the solid states of carbon. Graphite is the other. Both diamond and graphite consist of pure carbon, but differ from each other in the arrangement of the atoms.

Carbon (whether diamond or graphite) can indeed become liquid, namely from a temperature of about 4500 °C and a pressure of about 100 000 atm.

At that pressure and temperature there is an equilibrium between liquid carbon, graphite and diamond. This is a so-called triple point.

These are not direct circumstances that you encounter every day!

Why does diamond disintegrate when heated to carbon atoms instead of melting first?

Answered by

Dr Etienne Jooken

Chemistry

Catholic University of Leuven
Old Market 13 3000 Leuven
https://www.kuleuven.be/

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